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  • B12H12 2–-Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity

    • 摘要：

      In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H12 2– were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8–286.3 °C; densities: 1.215–1.264 g cm–3). The results demonstrate their promising applications in bipropellant formulations.

    • 作者：

      Zejun Zhang;Yanqiang Zhang;Zhimin Li;Nianming Jiao;Long Liu;锁江 张

    • 刊名：

      European Journal of Inorganic Chemistry

    • 在线出版时间：

      2018-2-28